Charge excitations in LiV$_{2}$O$_{5}$ and NaV$_{2}$O$_{5}$: similarities and differences

Details Charge excitations in LiV$_{2}$O$_{5}$ and NaV$_{2}$O$_{5}$: similarities and differences Charge excitations in LiV$_{2}$O$_{5}$ and NaV$_{2}$O$_{5}$: similarities and differences

2001-06-12

arxiv.org/abs/cond-mat/0106213v3

Phys. Rev. B 64, 241103(R) (2001)

Physics

Condensed Matter

Strongly Correlated Electrons

Scientific paper

10.1103/PhysRevB.64.241103

We calculate the optical conductivity of LiV$_{2}$O$_{5}$ and NaV$_{2}$O$_{5}$ using exact numerical diagonalization of a quarter-filled extended Hubbard model on a system of coupled ladders. In particular, electronic correlations are treated exactly, and a quantitative agreement between calculated and experimentally observed optical conductivity of these two vanadium oxides is presented. Furthermore, it is found that LiV$_{2}$O$_{5}$ differs from NaV$_{2}$O$_{5}$ not only in the charge ordering pattern but also in the nature of the inter-ladder coupling: In contrast to LiV$_{2}$O$_{5}$, in NaV$_{2}$O$_{5}$ neighboring ladders are coupled by a strong Coulomb repulsion, and not by inter-ladder hopping.

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