Calculation of the orthorhombic E-parameter in EPR for d3 spin systems

Details Calculation of the orthorhombic E-parameter in EPR for d3 spin systems Calculation of the orthorhombic E-parameter in EPR for d3 spin systems

2011-05-03

arxiv.org/abs/1105.0616v1

Physics

Condensed Matter

Materials Science

5 pages, 13 references

Scientific paper

Third order perturbation theory is used to calculate the orthorhombic
spin-Hamiltonian zero-field E-term for octahedrally surrounded d3 spin systems
(S = 3/2) in strong axial fields in the presence of a weak orthorhombic
component.

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