Bulk and shear relaxation in glasses and highly viscous liquids

Physics – Condensed Matter – Disordered Systems and Neural Networks

Scientific paper

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6 pages, 2 figures, 53 references; version after understanding the Prigogine-Defay ratio at the glass transition in the accomp

Scientific paper

The ratio between the couplings of a relaxational process to compression and shear, respectively, is calculated in the Eshelby picture of structural rearrangements within a surrounding elastic matrix, assuming a constant density of stable structures in distortion space. The result is compared to experimental data for the low-temperature tunneling states in glasses and to Prigogine-Defay data at the glass transition from the literature.

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