Bridge Hopping on Conducting Polymers in Solution

Details Bridge Hopping on Conducting Polymers in Solution Bridge Hopping on Conducting Polymers in Solution

2000-10-06

arxiv.org/abs/cond-mat/0010115v1

Physics

Condensed Matter

Soft Condensed Matter

RevTeX 12 pages + 2 Postscript figures

Scientific paper

10.1209/epl/i2001-00381-x

Configurational fluctuations of conducting polymers in solution can bring into proximity monomers which are distant from each other along the backbone. Electrons can hop between these monomers across the "bridges" so formed. We show how this can lead to (i) a collapse transition for metallic polymers, and (ii) to the observed dramatic efficiency of acceptor molecules for quenching fluorescence in semiconducting polymers.

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