Physics – Condensed Matter – Materials Science
Scientific paper
2005-02-14
Phys. Rev. Lett. 94, 106101 (2005).
Physics
Condensed Matter
Materials Science
RevTex4, 4 pages, 4 figures, Fig. 2 of high quality available upon request, to appear in Phys. Rev. Lett
Scientific paper
10.1103/PhysRevLett.94.106101
We report scanning tunneling microscopy observations of Ge deposited on the Si(111)-7x7 surface for a sequence of sub-monolayer coverages. We demonstrate that Ge atoms replace so-called Si adatoms. Initially, the replacements are random, but distinct patterns emerge and evolve with increasing coverage, till small islands begin to form. Corner adatom sites in the faulted half unit cells are preferred. First-principles density functional calculations find that adatom substitution competes energetically with a high-coordination bridge site, but atoms occupying the latter sites are highly mobile. Thus, the observed structures are indeed more thermodynamically stable.
Gao Hong-Jun
Guo Hong-Mei
Pantelides Sokrates T.
Wang Li-Yan
Wang Sanwu
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