Behavior of Optical Phonons near the Diffuse Phase Transition in Relaxor Ferroelectric PbMg1/3Ta2/3O3

Physics – Condensed Matter – Materials Science

Scientific paper

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Scientific paper

10.1103/PhysRevB.70.172101

Raman scattering in relaxor ferroelectric PbMg1/3Ta2/3O3 (PMT) was investigated in the single crystalline form in the temperature range of 20 - 295 K. Anomalous temperature dependence of the integrated intensity and the Raman line contours were found at the diffuse phase transition. A correlation between the anomalies in the integrated intensities and the dispersion of the dielectric response was observed. The distortions of Raman lines with decreasing temperature are discussed.

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