Band Formation during Gaseous Diffusion in Aerogels

Physics – Condensed Matter – Soft Condensed Matter

Scientific paper

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7 pages RevTex and 8 figures. Figs. 4-8 in Postscript, Figs. 1-3 on request from authors

Scientific paper

10.1103/PhysRevE.57.6767

We study experimentally how gaseous HCl and NH_3 diffuse from opposite sides of and react in silica aerogel rods with porosity of 92 % and average pore size of about 50 nm. The reaction leads to solid NH_4Cl, which is deposited in thin sheet-like structures. We present a numerical study of the phenomenon. Due to the difference in boundary conditions between this system and those usually studied, we find the sheet-like structures in the aerogel to differ significantly from older studies. The influence of random nucleation centers and inhomogeneities in the aerogel is studied numerically.

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