Attraction between like-charged colloidal particles induced by a surface a density - functional analysis

Details Attraction between like-charged colloidal particles induced by a surface a density - functional analysis Attraction between like-charged colloidal particles induced by a surface a density - functional analysis

1998-09-14

arxiv.org/abs/cond-mat/9809191v1

Physics

Condensed Matter

Soft Condensed Matter

12 pages including 2 figures. submitted to physical review letters

Scientific paper

10.1209/epl/i1999-00276-4

We show that the first non-linear correction to the linearised
Poisson-Boltzman n (or DLVO) theory of effective pair interactions between
charge-stabilised, co lloidal particles near a charged wall leads to an
attractive component of entro pic origin. The position and depth of the
potential compare favourably with rec ent experimental measurements

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