Physics – Condensed Matter
Scientific paper
1996-07-10
Phys. Rev. E, 51(3, pt. B) (1995) pp. 2363-7
Physics
Condensed Matter
12 pages, LaTeX, Revised: missing ref. for important paper by G. Oshanin and A. Blumen was added and minor misprints corrected
Scientific paper
10.1103/PhysRevE.51.2363
We present simple explicit estimates for the apparent reaction rate constant for three molecular reactions, which are important in catalysis. For small concentrations and $d> 1$, the apparent reaction rate constant depends only on the diffusion coefficients and sizes of the particles. For small concentrations and $d\le 1$, it is also time -- dependent. For large concentrations, it gains the dependence on concentrations.
Burlatsky Sergei F.
Moreau Mathieu
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