Antiferromagnetic fluctuations in the normal state of LiFeAs

Physics – Condensed Matter – Superconductivity

Scientific paper

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5 pages, 3 figures, thoroughly revised version with refined experimental data, accepted for publication as a Rapid Communicati

Scientific paper

10.1103/PhysRevB.81.140511

We present a detailed study of 75As NMR Knight shift and spin-lattice relaxation rate in the normal state of stoichiometric polycrystalline LiFeAs. Our analysis of the Korringa relation suggests that LiFeAs exhibits strong antiferromagnetic fluctuations, if transferred hyperfine coupling is a dominant interaction between 75As nuclei and Fe electronic spins, whereas for an on-site hyperfine coupling scenario, these are weaker, but still present to account for our experimental observations. Density-functional calculations of electric field gradient correctly reproduce the experimental values for both 75As and 7Li sites.

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