Anomalous dynamics of confined water at low hydration

Physics – Condensed Matter – Statistical Mechanics

Scientific paper

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6 pages with 9 figures. RevTeX. Accepted for publication in J. Phys. Condens. Matt

Scientific paper

10.1088/0953-8984/15/45/002

The mobility of water molecules confined in a silica pore is studied by computer simulation in the low hydration regime, where most of the molecules reside close to the hydrophilic substrate. A layer analysis of the single particle dynamics of these molecules shows an anomalous diffusion with a sublinear behaviour at long time. This behaviour is strictly connected to the long time decay of the residence time distribution analogously to water at contact with proteins.

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