Anisotropic Etching and Nanoribbon Formation in Single-Layer Graphene

Physics – Condensed Matter – Materials Science

Scientific paper

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Nano Letters 10.1021/nl900811r

Scientific paper

10.1021/nl900811r

We demonstrate anisotropic etching of single-layer graphene by thermally-activated nickel nanoparticles. Using this technique, we obtain sub-10nm nanoribbons and other graphene nanostructures with edges aligned along a single crystallographic direction. We observe a new catalytic channeling behavior, whereby etched cuts do not intersect, resulting in continuously connected geometries. Raman spectroscopy and electronic measurements show that the quality of the graphene is resilient under the etching conditions, indicating that this method may serve as a powerful technique to produce graphene nanocircuits with well-defined crystallographic edges.

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