Physics – Condensed Matter – Statistical Mechanics
Scientific paper
2011-04-29
Physics
Condensed Matter
Statistical Mechanics
15 pages, 8 figures, submitted to Phys. Rev. E
Scientific paper
A stochastic model of autocatalytic chemical reactions is studied both numerically and analytically. The van Kampen perturbative scheme is implemented, beyond the second order approximation, so to capture the non Gaussianity traits as displayed by the simulations. The method is targeted to the characterization of the third moments of the distribution of fluctuations, originating from a system of four populations in mutual interaction. The theory predictions agree well with the simulations, pointing to the validity of the van Kampen expansion beyond the conventional Gaussian solution.
Barletti Luigi
Cianci Claudia
Fanelli Duccio
Patti Francesca Di
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