An iron(III) phosphonate cluster containing a nonanuclear ring

Physics – Condensed Matter – Strongly Correlated Electrons

Scientific paper

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3 pages, 3 figures

Scientific paper

This communication reports the first example of cyclic ferric clusters with
an odd number of iron atoms capped by phosphonate ligands, namely,
[Fe9(m-OH)7(m-O)2(O3PC6H9)8-(py)12]. The magnetic studies support a S = 1/2
ground state with an exchange coupling constant of about J = -30 K.

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