Physics – Condensed Matter – Soft Condensed Matter
Scientific paper
2004-10-23
Phys. Rev. E71, 041803 (2005) (12 pages)
Physics
Condensed Matter
Soft Condensed Matter
13 pages, 10 figures, 1 table
Scientific paper
10.1103/PhysRevE.71.041803
Aging dynamics in thin films of poly(methyl methacrylate) (PMMA) have been investigated through dielectric measurements for different types of aging processes. The dielectric constant was found to decrease with increasing aging time at an aging temperature in many cases. An increase in the dielectric constant was also observed in the long time region ($\ge$11h) near the glass transition temperature for thin films with thickness less than 26nm. In the constant rate mode including a temporary stop at a temperature $T_a$, the memory of the aging at $T_a$ was found to be kept and then to be recalled during the subsequent heating process. In the negative temperature cycling process, a strong rejuvenation effect has been observed after the temperature shift from the initial temperature $T_1$ to the second temperature $T_2$($=T_1+\Delta T$) when $\Delta T\approx -20$K. Furthermore, a full memory effect has also been observed for the temperature shift from $T_2$ to $T_1$. This suggests that the aging at $T_1$ is totally independent of that at $T_2$ for $\Delta T\approx -20$K. As $|\Delta T|$ decreases, the independence of the aging between the two temperatures was found to be weaken, $i.e.,$ the effective time, which is a measure of the contribution of the aging at $T_1$ to that at $T_2$, is a decreasing function of $|\Delta T|$ in the negative region of $\Delta T$. As the film thickness decreases from 514nm to 26nm, the $|\Delta T|$ dependence of the effective time was found to become much stronger. The contribution of the aging at $T_2$ to that at $T_1$ disappears more rapidly with increasing $|\Delta T|$ in thin film geometry than in the bulk state.
Fukao Koji
Sakamoto Aiko
No associations
LandOfFree
Aging phenomena in PMMA thin films -- memory and rejuvenation effects does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.
If you have personal experience with Aging phenomena in PMMA thin films -- memory and rejuvenation effects, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Aging phenomena in PMMA thin films -- memory and rejuvenation effects will most certainly appreciate the feedback.
Profile ID: LFWR-SCP-O-485200