Physics – Condensed Matter – Materials Science
Scientific paper
2002-12-13
Physics
Condensed Matter
Materials Science
Submitted to Solid State Communications, 4 figures
Scientific paper
10.1016/S0038-1098(03)00480-0
The aging of a nanocrystalline equiatomic ZnSe alloy produced by mechanical alloying was investigated using X-ray diffraction (XRD) and differential scanning calorimetry (DSC) techniques. The measured XRD patterns showed that Se atoms located at interfacial component migrated with aging giving raise to a crystalline selenium (c-Se) phase. DSC spectra of heat-treated samples at temperatures above 221oC followed by quenching showed that the c-Se particles changed to the amorphous state. It was also observed that the as-milled and aged samples are highly hydrophilic. The lattice parameters and the average crystallite sizes were calculated as a function of time of aging and temperature of heat treatment.
de Campos E. M. C.
de Lima João Cardoso
Gasperini A. A. M.
Grandi Tarciso Antonio
Machado Kleber D.
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