Adsorption of polydisperse polymer chains

Details Adsorption of polydisperse polymer chains Adsorption of polydisperse polymer chains

1999-01-04

arxiv.org/abs/cond-mat/9901014v1

Journal of Chemical Physics v111, p2255-2258 (1999)

Physics

Condensed Matter

Soft Condensed Matter

4 pages, 1 figure

Scientific paper

10.1063/1.479496

The adsorption of polydisperse ideal polymer chains is shown to be sensitive to the large N tail of the distribution of chains. If and only if the number of chains decays more slowly than exponentially then there is an adsorption transition like that of monodisperse infinite chains. If the number decays exponentially the adsorption density diverges continuously at a temperature which is a function of the mean chain length. At low coverages, chains with repulsive monomer--monomer interactions show the same qualitative behaviour

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