A van der Waals free energy in electrolytes revisited

Details A van der Waals free energy in electrolytes revisited A van der Waals free energy in electrolytes revisited

2005-09-15

arxiv.org/abs/cond-mat/0509411v2

Eur.Phys.J. E 19, 1 (2006)

Physics

Condensed Matter

Soft Condensed Matter

7 pages. PACS numbers updated. References updated

Scientific paper

10.1140/epje/e2005-00056-3

A system of three electrolytes separated by two parallel planes is considered. Each region is described by a dielectric constant and a Coulomb fluid in the Debye-H\"uckel regime. In their book Dispersion Forces, Mahanty and Ninham have given the van der Waals free energy of this system. We rederive this free energy by a different method, using linear response theory and the electrostatic Maxwell stress tensor for obtaining the dispersion force.

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