Physics – Fluid Dynamics
Scientific paper
Oct 1992
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1992gecoa..56.3611b&link_type=abstract
Geochimica et Cosmochimica Acta (ISSN 0016-7037), vol. 56, no. 10, p. 3611-3626.
Physics
Fluid Dynamics
15
Computerized Simulation, Equations Of State, Fluid Dynamics, Intermolecular Forces, Planetary Mantles, Ammonia, Argon, Carbon Dioxide, Carbon Monoxide, Carbonyl Compounds, Hydrogen, Hydrogen Sulfide, Methane, Nitrogen, Oxygen, Sulfur, Sulfur Dioxides, Water
Scientific paper
A unified equation of state (EOS) is derived for 13 gases (including H2O, CO2, CH4, CO, O2, H2, Ar, N2, NH3, H2S, SO2, COS, and S2) in C-H-O-N-S-Ar system, on the basis of molecular dynamical simulated PVT data, assuming these species to be alpha-exponential-6 fluids at high temperature and pressure. The EOS equation is parameterized for these gases in the ranges of temperature and pressure 400-4000 K and 5-1000 kbar, respectively. It is shown that the equation reproduces most of the available experimental data in the limits of experimental accuracy of volume measurements.
Belonoshko Anatoly B.
Saxena Surendra K.
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