Physics – Condensed Matter – Soft Condensed Matter
Scientific paper
2005-06-28
Langmuir, 22 (2006) pp. 163--168
Physics
Condensed Matter
Soft Condensed Matter
11 pages, 5 figures
Scientific paper
10.1021/la0517282
We consider a microscopic model for the failure of soft adhesives in tension based on ideas of bond rupture under dynamic loading. Focusing on adhesive failure under loading at constant velocity, we demonstrate that bi-modal curves of stress against strain may occur due to effects of finite polymer chain or bond length and characterise the loading conditions under which such bi-modal behaviour is observed. The results of this analysis are in qualitative agreement with experiments performed on unconfined adhesives in which failure does not occur by cavitation.
Mahadevan L.
Vella Dominic
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