A perturbative approach to J mixing in f-electron systems: Application to actinide dioxides

Details A perturbative approach to J mixing in f-electron systems: Application to actinide dioxides A perturbative approach to J mixing in f-electron systems: Application to actinide dioxides

2004-11-25

arxiv.org/abs/cond-mat/0411649v1

Phys. Rev. B 71, 054405 (2005)

Physics

Condensed Matter

Other Condensed Matter

16 pages + 4 figures; will appear http://prb.aps.org

Scientific paper

10.1103/PhysRevB.71.054405

We present a perturbative model for crystal-field calculations, which keeps into account the possible mixing of states labelled by different quantum number J. Analytical J-mixing results are obtained for a Hamiltonian of cubic symmetry and used to interpret published experimental data for actinide dioxides. A unified picture for all the considered compounds is proposed by taking into account the scaling properties of the crystal-field potential.

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