A One-Dimensional Coordination Polymer, BBDTA-InCl4; Possible Spin-Peierls Transition with High Critical Temperature of 108 K

Details A One-Dimensional Coordination Polymer, BBDTA-InCl4; Possible Spin-Peierls Transition with High Critical Temperature of 108 K A One-Dimensional Coordination Polymer, BBDTA-InCl4; Possible Spin-Peierls Transition with High Critical Temperature of 108 K

2005-10-10

arxiv.org/abs/cond-mat/0510231v1

Physics

Condensed Matter

Materials Science

Submited to PRB

Scientific paper

We have studied the crystal structure and magnetic properties of the organic radical cation salt, BBDTA-InCl4. This material formed a one-dimensional coordination polymer, whose structure was characteristic of inorganic spin-Peierls materials. Magnetic measurements indicated the spin-Peierls transition like behavior at 108 K, which was higher than those typically observed for the other organic spin-Peierls materials. The structural aspects of the lattice distortion from X-ray diffraction measurements at 50 K have been discussed.

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