A novel approach to the crystal-field theory - the orbital magnetism in 3d-ion compounds

Details A novel approach to the crystal-field theory - the orbital magnetism in 3d-ion compounds A novel approach to the crystal-field theory - the orbital magnetism in 3d-ion compounds

2003-07-23

arxiv.org/abs/cond-mat/0307575v1

Acta Physica 1 (2006) 3

Physics

Condensed Matter

Strongly Correlated Electrons

9 pages in RevTex4, 3 figs

Scientific paper

We point out that the orbital magnetism has to be taken into account in the description of real 3d-ion compounds. According to the developed by us the Quantum-Atomistic Solid-State (QUASST) theory in compounds containing open 3d-/4f-/5f-shell atoms there exists a discrete atomic-like low-energy electronic structure that predominantly determines electronic and magnetic properties of the whole compound. The relatively weak intra-atomic spin-orbit coupling is fundamentally important as it governs the low-energy discrete electronic structure.

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