Physics – Condensed Matter – Statistical Mechanics
Scientific paper
2000-02-03
Physics
Condensed Matter
Statistical Mechanics
22 pages, 7 figures
Scientific paper
A recent description of the motion of atoms in a classical monatomic system in liquid and supercooled liquid states divides the motion into two parts: oscillations within a given many-particle potential valley, and transit motion which carries the system from one many-particle valley to another. Building on this picture, we construct a model for the trajectory of an average atom in the system. The trajectory consists of oscillations at the normal-mode distribution of frequencies, representing motion within a fluctuating single-particle well, interspersed with position- and velocity-conserving transits to similar adjacent wells. For the supercooled liquid in nondiffusing states, the model gives velocity and displacement autocorrelation functions which exactly match those found in the many-particle harmonic approximation, and which are known to agree almost precisely with molecular dynamics (MD) simulations of liquid Na. At higher temperatures, by allowing transits to proceed at a temperature-dependent rate, the model gives velocity autocorrelation functions which are also in remarkably good agreement with MD simulations of Na at up to three times its melting temperature. Two independent processes in the model relax velocity autocorrelations: (a) dephasing due to the presence of many frequency components, which operates at all temperatures but which produces zero diffusion, and (b) the transit process, which increases with increasing temperature and which produces diffusion.
Chisolm Eric D.
Wallace Duane C.
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