A brief critique of the Adam-Gibbs entropy model

Details A brief critique of the Adam-Gibbs entropy model A brief critique of the Adam-Gibbs entropy model

2009-01-14

arxiv.org/abs/0901.2104v1

J. Non-Cryst. Solids 355, 624 (2009).

Physics

Condensed Matter

Soft Condensed Matter

Scientific paper

This paper critically reviews the entropy model proposed by Adam and Gibbs in 1965 for explaining the dramatic temperature dependence of glass-forming liquids' average relaxation time, one of the most influential models during the last three decades. We discuss the Adam-Gibbs model's theoretical bases as well as the reported experimental model confirmations; in the process of doing this a number of problems with the model are identified.

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