33SO2: Interstellar Identification and Laboratory Measurements

Physics

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Scientific paper

The rotational spectrum of33S isotopically substituted sulfur dioxide,33SO2, has been measured up to nearly 1 THz. The combined analysis of these new data together with the published line frequencies resulted in refined molecular constants, such as the rotational (A= 59856.4723(62) MHz,B= 10318.3012(15) MHz,C= 8780.1363(15) MHz) and centrifugal distortion constants which yielded precise frequency predictions. The carrier of six previously unidentified interstellar lines in the Caltech molecular line survey in the 325-360 GHz band could be assigned to33SO2.

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