Thermodynamic picture of the glassy state

Details Thermodynamic picture of the glassy state Thermodynamic picture of the glassy state

2000-05-24

arxiv.org/abs/cond-mat/0005402v1

Physics

Condensed Matter

Disordered Systems and Neural Networks

Proceedings of the Conference "Unifying Concepts in Glass Physics", ICTP, Trieste, 15 - 18 September 1999

Scientific paper

10.1088/0953-8984/12/29/326

A picture for thermodynamics of the glassy state is introduced. It assumes that one extra parameter, the effective temperature, is needed to describe the glassy state. This explains the classical paradoxes concerning the Ehrenfest relations and the Prigogine-Defay ratio. As a second part, the approach connects the response of macroscopic observables to a field change with their temporal fluctuations, and with the fluctuation-dissipation relation, in a generalized non-equilibrium way.

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