Observations of depleted stratospheric NO2 following the Pinatubo volcanic eruption

Physics – Optics

Scientific paper

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Aerosols, Air Pollution, Nitrogen Oxides, Ozonometry, Stratosphere, Volcanoes, Atmospheric Optics, Nitric Acid, Ozone Depletion

Scientific paper

Following the eruption of Mount Pinatubo, and the subsequent transport of volcanic aerosol, significant depletions of stratospheric NO2 were observed at Lauder. New Zealand. The effect was more pronounced in NO2 columns measured at sunrise than those measured at sunset, and observed column amounts were reduced by more than 40 percent in October 1991. Concurrent ozone measurements obtained using the same technique were compared with Dobson measurements which confirmed that in October, apparent reduction of only 10-15 percent can be explained by geometric changes in scattering caused by the aerosols. A real depletion of NO2 is concluded to have occurred. NO2 levels at twilight are dependent on many factors, but these observations can provide supporting evidence for the hypothesis that heterogeneous processes convert N2O5 to HNO3 on the sulfate aerosol surfaces. If this proves to be the case it could, in the presence of current high chlorine levels and volcanically enhanced aerosol densities, lead to accelerated global ozone depletion.

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