Resonant X-Ray Scattering from CeB$_{6}$

Physics – Condensed Matter – Strongly Correlated Electrons

Scientific paper

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Latex, 10 pages, 12 figures. To be published in J. Phys. Soc. Jpn., Vol.71, No. 7 (2002)

Scientific paper

10.1143/JPSJ.71.1771

We calculate the resonant x-ray scattering (RXS) spectra near the Ce $L_{\rm III}$ absorption edge in CeB$_6$, on the basis of a microscopic model that the $4f$ states of Ce are atomic while the $5d$ states form an energy band with a reasonable density of states. In the initial state, we employ an effective Hamiltonian of Shiina {\it et al}. in the antiferro-quadrupole (AFQ) ordering phase, while we construct the wave function consistent with the neutron scattering experiment in the magnetic ground state. In the intermediate state, we take full account of the intra-atomic Coulomb interaction. Without assuming any lattice distortion, we obtain sufficient RXS intensities on the AFQ superlattice spot. We obtain the spectral shape, the temperature and magnetic field dependences in good agreement with the experiment, thus demonstrating the mechanism that the intensity is brought about by the modulation of $5d$ states through the anisotropic term of the $5d$-$4f$ Coulomb interaction. In the magnetic ground state, a small pre-edge peak is found by the $E_2$ process. On the magnetic superlattice spot, we get a finite but considerably small intensity. The magnetic form factor is briefly discussed.

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