Reaction Kinetics in a Tight Spot

Details Reaction Kinetics in a Tight Spot Reaction Kinetics in a Tight Spot

2005-05-22

arxiv.org/abs/cond-mat/0505541v1

Small 5 (2005) 502

Physics

Condensed Matter

Other Condensed Matter

Scientific paper

10.1002/smll.200400132

The standard analysis of reaction networks based on deterministic rate
equations fails in confined geometries, commonly encountered in fields such as
astrochemistry, thin film growth and cell biology. In these systems the small
reactant population implies anomalous behavior of reaction rates, which can be
accounted for only by following the full distribution of reactant numbers.

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