Spin Frank-Condon Effect

Details Spin Frank-Condon Effect Spin Frank-Condon Effect

2006-08-30

arxiv.org/abs/cond-mat/0608675v1

Physics

Condensed Matter

Strongly Correlated Electrons

13 pages, 4 figures, 2 tables, submitted to J. Phys. Chem. Chem. Phys

Scientific paper

10.1088/0953-8984/19/25/256208

The optical properties of a small magnetic cluster are studied in a magnetic version of Frank-Condon principle. This simple model is considered to show new basic physics and could be adopted to treat real problems. The energies and wavefunctions of the cluster are calculated for different spin configurations to evaluate the energies and the strengths of the allowed transitions from the relaxed excited states. The optical de-excitation energies for the likely scenarios are obtained in terms of the exchange parameters of the model.

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