Physics – Condensed Matter – Materials Science
Scientific paper
2008-11-10
AIChE Journal, 54 (2008) 2145-2154
Physics
Condensed Matter
Materials Science
Scientific paper
10.1002/aic.11540
In this paper, we develop a method for obtaining the approximate solution for the evolution of single-step transformations under non-isothermal conditions. We have applied it to many reaction models and obtained very simple analytical expressions for the shape of the corresponding transformation rate peaks. These analytical solutions represent a significant simplification of the system's description allowing easy curve fitting to experiment. A remarkable property is that the evolutions of the transformed fraction obtained at different heating rates are identical when time is scaled by a time constant. The accuracy achieved with our method is checked against several reaction models and different temperature dependencies of the transformation rate constant. It is shown that its accuracy is closely related with that of the Kissinger method.
Farjas Jordi
Roura Pere
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