The thermodynamical liquid-glass transition in a Lennard-Jones binary mixture

Details The thermodynamical liquid-glass transition in a Lennard-Jones binary mixture The thermodynamical liquid-glass transition in a Lennard-Jones binary mixture

1999-06-11

arxiv.org/abs/cond-mat/9906172v4

Phys. Rev. Lett. n.84, 306 (2000)

Physics

Condensed Matter

Soft Condensed Matter

5 pages, 3 figures, a minor mistake corrected and the main argument simplified. Numerical precision improved. Accepted for pub

Scientific paper

10.1103/PhysRevLett.84.306

We use the results derived in the framework of the replica approach to study the liquid-glass thermodynamic transition. The main results are rederived without using replicas and applied to the study of the Lennard-Jones binary mixture introduced by Kob and Andersen. We find that there is a phase transition due to the entropy crisis. We compute both analytically and numerically the value of the phase transition point $T_{K}$ and the specific heat in the low temperature phase.

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