Self-Consistent Field Theory of Multiply-Branched Block Copolymer Melts

Details Self-Consistent Field Theory of Multiply-Branched Block Copolymer Melts Self-Consistent Field Theory of Multiply-Branched Block Copolymer Melts

2005-01-18

arxiv.org/abs/cond-mat/0501404v1

Phys. Rev. E 71 (2005) 051801

Physics

Condensed Matter

Soft Condensed Matter

12 pages, 10 includes figures

Scientific paper

10.1103/PhysRevE.71.051801

We present a numerical algorithm to evaluate the self-consistent field theory for melts composed of block copolymers with multiply-branched architecture. We present results for the case of branched copolymers with doubly-functional groups for multiple branching generations. We discuss the stability of the cubic phase of spherical micelles, the A15 phase, as a consequence of tendency of the AB interfaces to conform to the polyhedral environment of the Voronoi cell of the micelle lattice.

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