Physics – Condensed Matter – Statistical Mechanics
Scientific paper
2004-09-23
Physics
Condensed Matter
Statistical Mechanics
To appear in the Proceedings of the 31st Workshop of the International School of Solid State Physics ``Complexity, Metastabili
Scientific paper
The cornerstones of Boltzmann-Gibbs and nonextensive statistical mechanics respectively are the entropies $S_{BG} \equiv -k \sum_{i=1}^W p_i \ln p_i $ and $S_{q}\equiv k (1-\sum_{i=1}^Wp_i^{q})/(q-1) (q\in{\mathbb R} ; S_1=S_{BG})$. Through them we revisit the concept of additivity, and illustrate the (not always clearly perceived) fact that (thermodynamical) extensivity has a well defined sense {\it only} if we specify the composition law that is being assumed for the subsystems (say $A$ and $B$). If the composition law is {\it not} explicitly indicated, it is {\it tacitly} assumed that $A$ and $B$ are {\it statistically independent}. In this case, it immediately follows that $S_{BG}(A+B)= S_{BG}(A)+S_{BG}(B)$, hence extensive, whereas $S_q(A+B)/k=[S_q(A)/k]+[S_q(B)/k]+(1-q)[S_q(A)/k][S_q(B)/k]$, hence nonextensive for $q \ne 1$. In the present paper we illustrate the remarkable changes that occur when $A$ and $B$ are {\it specially correlated}. Indeed, we show that, in such case, $S_q(A+B)=S_q(A)+S_q(B)$ for the appropriate value of $q$ (hence extensive), whereas $S_{BG}(A+B) \ne S_{BG}(A)+S_{BG}(B)$ (hence nonextensive).
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