Physics – Condensed Matter – Statistical Mechanics
Scientific paper
2004-01-10
Phys. Rev. E 68, 031204 (2003)
Physics
Condensed Matter
Statistical Mechanics
8 pages, 6 figures
Scientific paper
10.1103/PhysRevE.68.031204
We calculate using molecular dynamics simulations the transport properties of realistically modeled fluid argon at pressures up to $\simeq 50GPa$ and temperatures up to $3000K$. In this context we provide a critique of some newer theoretical predictions for the diffusion coefficients of liquids and a discussion of the Enskog theory relevance under two different adaptations: modified Enskog theory (MET) and effective diameter Enskog theory. We also analyze a number of experimental data for the thermal conductivity of monoatomic and small diatomic dense fluids.
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