Schematic models for dynamic yielding of sheared colloidal glasses

Physics – Condensed Matter – Soft Condensed Matter

Scientific paper

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33 pages, 10 figures; accepted for publication in Faraday Disc. 123 (2002); small numerical corrections

Scientific paper

The nonlinear rheological properties of dense suspensions are discussed within simplified models, suggested by a recent first principles approach to the model of Brownian particles in a constant-velocity-gradient solvent flow. Shear thinning of colloidal fluids and dynamical yielding of colloidal glasses arise from a competition between a slowing down of structural relaxation, because of particle interactions, and enhanced decorrelation of fluctuations, caused by the shear advection of density fluctuations. A mode coupling approach is developed to explore the shear-induced suppression of particle caging and the resulting speed-up of the structural relaxation.

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