Physics – Condensed Matter – Soft Condensed Matter
Scientific paper
2002-07-22
Physics
Condensed Matter
Soft Condensed Matter
33 pages, 10 figures; accepted for publication in Faraday Disc. 123 (2002); small numerical corrections
Scientific paper
The nonlinear rheological properties of dense suspensions are discussed within simplified models, suggested by a recent first principles approach to the model of Brownian particles in a constant-velocity-gradient solvent flow. Shear thinning of colloidal fluids and dynamical yielding of colloidal glasses arise from a competition between a slowing down of structural relaxation, because of particle interactions, and enhanced decorrelation of fluctuations, caused by the shear advection of density fluctuations. A mode coupling approach is developed to explore the shear-induced suppression of particle caging and the resulting speed-up of the structural relaxation.
Cates Michael E.
Fuchs Matthias
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