Surface-induced layer formation in polyelectrolytes

Details Surface-induced layer formation in polyelectrolytes Surface-induced layer formation in polyelectrolytes

1998-09-25

arxiv.org/abs/cond-mat/9809355v1

Physics

Condensed Matter

Soft Condensed Matter

6 pages, 3 figures, revtex, epsf, psfig

Scientific paper

10.1063/1.479093

We analyze, by means of an RPA calculation, the conditions under which a
mixture of oppositely charged polyelectrolytes can micro-segregate in the
neighborhood of a charged surface creating a layered structure. A number of
stable layers can be formed if the surface is sufficiently strongly charged
even at temperatures at which the bulk of the mixture is homogeneous.

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