Formation of Liesegang patterns: A spinodal decomposition scenario

Physics – Condensed Matter – Statistical Mechanics

Scientific paper

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RevTex, 4 pages, 4 eps figures

Scientific paper

10.1103/PhysRevLett.83.2880

Spinodal decomposition in the presence of a moving particle source is proposed as a mechanism for the formation of Liesegang bands. This mechanism yields a sequence of band positions x_n that obeys the spacing law x_n~Q(1+p)^n. The dependence of the parameters p and Q on the initial concentration of the reagents is determined and we find that the functional form of p is in agreement with the experimentally observed Matalon-Packter law.

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