Fourth virial coefficiens of asymmetric nonadditive hard-disc mixtures

Physics – Condensed Matter – Soft Condensed Matter

Scientific paper

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12 pages, 12 tables, 6 figures

Scientific paper

The fourth virial coefficient of asymmetric nonadditive binary mixtures of
hard discs is computed with a standard Monte Carlo method. Wide ranges of size
ratio ($0.05\leq q\leq 0.95$) and nonadditivity ($-0.5\leq \Delta\leq 0.5$) are
covered. A comparison is made between the numerical results and those that
follow from some theoretical developments.

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