Coexistence Curve Singularities at Critical End Points

Details Coexistence Curve Singularities at Critical End Points Coexistence Curve Singularities at Critical End Points

1997-01-16

arxiv.org/abs/cond-mat/9701113v1

Physics

Condensed Matter

Statistical Mechanics

9 pages Revtex, 3 figures. To appear in Phys. Rev. Lett

Scientific paper

10.1103/PhysRevLett.78.1488

We report an extensive Monte Carlo study of critical end point behaviour in a symmetrical binary fluid mixture. On the basis of general scaling arguments, singular behaviour is predicted in the diameter of the liquid-gas coexistence curve as the critical end point is approached. The simulation results show clear evidence for this singularity, as well as confirming a previously predicted singularity in the coexistence chemical potential. Both singularities should be detectable experimentally.

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