The Lennard-Jones-Devonshire cell model revisited

Details The Lennard-Jones-Devonshire cell model revisited The Lennard-Jones-Devonshire cell model revisited

2001-11-13

arxiv.org/abs/cond-mat/0111240v1

Physics

Condensed Matter

Soft Condensed Matter

5 pages, 3 figures, submitted to Mol. Phys

Scientific paper

10.1080/00268970110117133

We reanalyse the cell theory of Lennard-Jones and Devonshire and find that in
addition to the critical point originally reported for the 12-6 potential (and
widely quoted in standard textbooks), the model exhibits a further critical
point. We show that the latter is actually a more appropriate candidate for
liquid-gas criticality than the original critical point.

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