Interplay Between Time-Temperature-Transformation and the Liquid-Liquid Phase Transition in Water

Details Interplay Between Time-Temperature-Transformation and the Liquid-Liquid Phase Transition in Water Interplay Between Time-Temperature-Transformation and the Liquid-Liquid Phase Transition in Water

2002-02-06

arxiv.org/abs/cond-mat/0202094v1

Phys. Rev. Lett. 88, 195701 (2002)

Physics

Condensed Matter

Soft Condensed Matter

RevTeX4, 4 pages, 4 eps figures

Scientific paper

10.1103/PhysRevLett.88.195701

We study the TIP5P water model proposed by Mahoney and Jorgensen, which is closer to real water than previously-proposed classical pairwise additive potentials. We simulate the model in a wide range of deeply supercooled states and find (i) the existence of a non-monotonic ``nose-shaped'' temperature of maximum density line and a non-reentrant spinodal, (ii) the presence of a low temperature phase transition, (iii) the free evolution of bulk water to ice, and (iv) the time-temperature-transformation curves at different densities.

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