Physics – Condensed Matter – Soft Condensed Matter
Scientific paper
1997-02-14
Physics
Condensed Matter
Soft Condensed Matter
14 pages,4 figures
Scientific paper
Reptation governs motion of long polymers through a confining environment. Slack enters at the ends and diffuses along the polymer as stored length. The rate at which stored length diffuses limits the speed at which the chain can drift. This paper relates the rate of stored length diffusion to the conformation of the tube within which the polymer is confined. In the scaling limit of long polymer chains and weak applied electric fields, holding the product of polymer length times field finite, the tube length and stored length density take on their zero-field values. The drift velocity then depends only on the the polymer's end-to-end separation in the direction of the field.
Al-Lehyani Ibrahim
Widom Michael
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