Disorder and relaxation mode in the lattice dynamics of PbMg$_{1/3}$Nb$_{2/3}$O$_3$ relaxor ferroelectric

Physics – Condensed Matter – Materials Science

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Scientific paper

10.1103/PhysRevB.69.092105

The low-energy part of vibration spectrum in PbMg$_{1/3}$Nb$_{2/3}$O$_3$ relaxor ferroelectric was studied by inelastic neutron scattering. We observed the coexistence of a resolution-limited central peak with strong quasielastic scattering. The line-width of the quasielastic component follows a $\Gamma_0+Dq^2$ dependence. We find that $\Gamma_0$ is temperature-dependent. The relaxation time follows the Arrhenius law well. The presence of a relaxation mode associated with quasi-elastic scattering in PMN indicates that order-disorder behaviour plays an important r\^ole in the dynamics of diffuse phase transitions.

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