Physics – Condensed Matter – Strongly Correlated Electrons
Scientific paper
2001-10-15
Physics
Condensed Matter
Strongly Correlated Electrons
To be published in J. Solid State Chem
Scientific paper
10.1006/jssc.2001.9420
The novel spin-chain cobalt oxide Sr5Pb3CoO12 [P-62m, a = 10.1093(2) A and c = 3.562 51(9) A at 295 K] is reported. Polycrystalline sample of the compound was studied by neutron diffraction (at 6 and 295 K) and magnetic susceptibility measurements (5 to 390 K). The cobalt oxide was found to be analogous to the copper oxide Sr5Pb3CoO12, which is comprised of magnetic-linear chains at inter-chain distance of 10 A. Although the cobalt oxide chains (mu_eff of 3.64 mu_B per Co) are substantially antiferromagnetic (theta_W = -38.8 K), neither low-dimensional magnetism nor long-range ordering has been found; a local-structure disorder in the chains might impact on the magnetism. This compound is highly electrically insulating.
Huang Qingzhen
Takayama-Muromachi Eiji
Yamaura Kazunari
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