Ultrasonic investigation of the interaction hydrogen-dislocations in copper crystals

Physics – Condensed Matter – Materials Science

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Scientific paper

In this paper we present experimental data of ultrasonic velocity and attenuation obtained in a high purity crystalline sample of cooper hydrogenated by gaseous charge. The sample is oriented in the <111> crystallographic direction and aged for this work in three stages between 64 and 97 days. The results indicate that the hydrogen is mainly segregated at the dislocation core, inhibiting the Hydrogen Snoek-K\"oster relaxations verified at earlier aging stages. Despite of this, a contribution to viscosity in the kink-chain resonance is provided by the mobile hydrogen in the dislocations core by its side movement along the dislocation line. At temperatures at which the hydrogen begins to freeze in the lattice the geometrical kinks find a gradual increase on the hindering of their movements along dislocation lines, becoming immobile when the hydrogen is completely frozen in the crystal, anchoring the dislocations in short loops. Although the viscosity associated with the mobile hydrogen is removed, the resonance associated with geometrical kinks is not completely cancelled. The interaction hydrogen-dislocation can be fully described in terms of kinks in dislocations.

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