Spectral Representation for the Effective Macroscopic Response of a Polycrystal: Application to Third-Order Nonlinear Susceptibility

Physics – Condensed Matter

Scientific paper

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To be published in J. Phys.: Condens. Matter; 19 pages, 3 figures. Axis labels may not be displayed properly for some figures

Scientific paper

10.1088/0953-8984/11/50/324

We extend the spectral theory used for the calculation of the effective linear response functions of composites to the case of a polycrystalline material with uniaxially anisotropic microscopic symmetry. As an application, we combine these results with a nonlinear decoupling approximation as modified by Ma et al., to calculate the third-order nonlinear optical susceptibility of a uniaxial polycrystal, assuming that the effective dielectric function of the polycrystal can be calculated within the effective-medium approximation.

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