Comment on Phys. Stat. Sol. (b) 236 (2003) 281 paper by A. M. Oles "Orbital ordering and orbital fluctuations in transition metal oxides"

Details Comment on Phys. Stat. Sol. (b) 236 (2003) 281 paper by A. M. Oles "Orbital ordering and orbital fluctuations in transition metal oxides" Comment on Phys. Stat. Sol. (b) 236 (2003) 281 paper by A. M. Oles "Orbital ordering and orbital fluctuations in transition metal oxides"

2004-09-30

arxiv.org/abs/cond-mat/0409777v1

Physics

Condensed Matter

Strongly Correlated Electrons

2 pages in RevTeX 4, submitted to Phys. Stat. Sol. B 2004-06-28, registered under No 04062802

Scientific paper

We argue that the 3A2 state considered by Oles in Phys. Stat. Sol. (b) 236
(2003) 281 for the d2 system occurring in the V3+ ion in V2O3 and LaVO3 as well
as in Ti2+ ion in TiO and in many other oxides is wrong. The proper ground
state is 3T1g - its 9-fold degeneracy is further split in a crystal by
intra-atomic spin-orbit interactions and lattice distortions.

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