Physics – Condensed Matter – Statistical Mechanics
Scientific paper
2006-06-27
J. Chem. Phys. 125: 094904, 2006
Physics
Condensed Matter
Statistical Mechanics
23 pages, 1 figure
Scientific paper
10.1063/1.2339015
We determine the density expansion of the radius of gyration, of the hydrodynamic radius, and of the end-to-end distance for a monodisperse polymer solution in good-solvent conditions. We consider the scaling limit (large degree of polymerization), including the leading scaling corrections. Using the expected large-concentration behavior, we extrapolate these low-density expansions outside the dilute regime, obtaining a prediction for the radii for any concentration in the semidilute region. For the radius of gyration, comparison with field-theoretical predictions shows that the relative error should be at most 5% in the limit of very large polymer concentrations.
Caracciolo Sergio
Mognetti Bortolo Matteo
Pelissetto Andrea
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